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Beilstein J. Org. Chem. 2019, 15, 1534–1544, doi:10.3762/bjoc.15.156
Graphical Abstract
Figure 1: Some examples for artificial C2- and C3-symmetric platforms based on Lissoclinum cyclopeptide alkal...
Figure 2: a) Principle of a chiral foldable platform and container based on Lissoclinum cyclopeptide alkaloid...
Scheme 1: Synthesis of the chiral foldable container 10. Reaction conditions: i) FDPP, iPr2NEt, CH3CN, 90%; i...
Figure 3: Molecular structures of trans,trans-10 (left), cis,trans-10 (middle) and cis,cis-10 (right) calcula...
Figure 4: UV spectra of the foldable container 10 in acetonitrile after synthesis (blue), after irradiation w...
Figure 5: Section from the 1H NMR spectra of the foldable container 10 in MeOD at 600 MHz: a) after synthesis...
Figure 6: HPLC spectra (ReproSil Phenyl, 5 μm, 250 × 8 mm; methanol) of trans,trans-10 (blue), cis,trans-10 (...
Figure 7: CD spectra of trans,trans-10 (blue), cis,trans-10 (green), and cis,cis-10 (red) in methanol (c = 3....
Figure 8: DOSY NMR spectra (500 MHz in MeOD at 25 °C) of the foldable container 10 after synthesis (left) and...
Beilstein J. Org. Chem. 2019, 15, 874–880, doi:10.3762/bjoc.15.85
Figure 1: Selected examples of bioactive molecules based on the pyrazolopyridine framework.
Scheme 1: Synthesis of pyrazolopyridines containing chromone 4a–m through a multicomponent reaction.
Figure 2: ORTEP Structure of compound 4a and intermolecular hydrogen bonding; the ellipsoid probability level...
Figure 3: Structures of synthesized pyrazolopyridines 4a–m. Reaction conditions: 3-formylchromone derivatives...
Scheme 2: The proposed mechanism for the synthesis of pyrazolopyridines derivatives 4a–m and 5a–d.
Figure 4: Structures of synthesized compounds 5a–d.